You can verify the certificate path with OpenSSL in a *NIX command line, the following is an example of the procedure:
# trying to connect to a server we suspect has a bad cert chain installed
$ openssl s_client -connect server01.badintermediate.domain.com:1999 -tls1_2
CONNECTED(00000005)
depth=0 C = US, ST = Florida, L = Miami, O = "Example Company, Inc.", CN = *.domain.com
verify error:num=20:unable to get local issuer certificate
verify return:1
depth=0 C = US, ST = Florida, L = Miami, O = "Example Company, Inc.", CN = *.domain.com
verify error:num=21:unable to verify the first certificate
verify return:1